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ZDMA/炭黑增強(qiáng)HNBR硅烷改性聚氨酯密封膠
- 發(fā)布時(shí)間 : 2025-6-7 11:04:56
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(Summary description)Customized SILICONE STRUCTURAL SEALANT from China manufacturer refers to the adhesive with high strength, can bear large load, aging resistance, fatigue resistance and corrosion resistance, and has stable performance within the expected life. It is suitable for bearing the bonding of strong structural parts. Non structural adhesive has low strength and poor durability. It can only be used for bonding, sealing and fixing of ordinary and temporary properties, and cannot be used for structural adhesive bonding. NEUTRAL SILICONE WETHERPROOF SEALANT from China manufacturer is a structural adhesive with waterproof function. Silicone glue refers to the adhesive based on silicone rubber. According to different functions, it can be divided into structural adhesive, potting adhesive, sealant, thermal conductive adhesive, flame retardant adhesive and so on.
ZDMA/炭黑增強(qiáng)HNBR硅烷改性聚氨酯密封膠
(Summary description)Customized SILICONE STRUCTURAL SEALANT from China manufacturer refers to the adhesive with high strength, can bear large load, aging resistance, fatigue resistance and corrosion resistance, and has stable performance within the expected life. It is suitable for bearing the bonding of strong structural parts. Non structural adhesive has low strength and poor durability. It can only be used for bonding, sealing and fixing of ordinary and temporary properties, and cannot be used for structural adhesive bonding. NEUTRAL SILICONE WETHERPROOF SEALANT from China manufacturer is a structural adhesive with waterproof function. Silicone glue refers to the adhesive based on silicone rubber. According to different functions, it can be divided into structural adhesive, potting adhesive, sealant, thermal conductive adhesive, flame retardant adhesive and so on.
- 發(fā)布時(shí)間 : 2025-6-7 11:04:56
- Views:
分別以炭黑、甲基丙烯酸鋅(ZDMA)及兩者并用為增強(qiáng)劑填充氫化丁睛稼膠(HNBR),研究了HNBR混煉膠的硫化特征,考察了增強(qiáng)劑種類、炭黑與ZDMA并用比、溫度對HNBR硅烷改性聚氨酯密封膠物理機(jī)械性能的影響,并評(píng)價(jià)了用ZDMA/炭黑增強(qiáng)HNBR制得的封隔器膠筒的高溫高壓密封性能。結(jié)果表明,相比炭黑,ZDMA增強(qiáng)HNBR混煉膠的焦燒時(shí)間和正硫化時(shí)間均大幅度縮短,最大轉(zhuǎn)矩大幅度提高;常溫下炭黑的粒徑越小,其填充HNBR硅烷改性聚氨酯密封膠的物理機(jī)械性能越好,但劣于ZDMA填充HNBR硅烷改性聚氨酯密封膠,ZDMA/炭黑填充HNBR硅烷改性聚氨酯密封膠的拉伸強(qiáng)度比純ZDMA填充HNBR硅烷改性聚氨酯密封膠低,但同時(shí)永久變形也降低;在高溫下,ZDMA/炭黑增強(qiáng)HNBR硅烷改性聚氨酯密封膠的拉伸強(qiáng)度和撕裂強(qiáng)度具有較高的保持率,且隨著溫度的升高,降低速率低于純ZDMA增強(qiáng)HNBR硅烷改性聚氨酯密封膠,但前者的拉斷伸長率高于后者,而永久變形小于后者;ZDMA/炭黑增強(qiáng)HNBR硅烷改性聚氨酯密封膠具有優(yōu)異的耐熱空氣老化性能,且以其制得的封隔器膠筒能夠在180 ℃30MPa的壓差下保持較好的密封效果。
氫化丁睛橡膠(HNBR)是丁睛橡膠經(jīng)過選擇性加氫變成具有飽和結(jié)構(gòu)的特種聚合物,它既具有優(yōu)異的耐油和耐熱性能,又表現(xiàn)出更高的拉伸強(qiáng)度和耐磨性能,在采油工程中逐漸得到廣泛應(yīng)用。在HNBR的加工與性能研究中常用的增強(qiáng)劑為炭黑,其價(jià)格便宜,但用其增強(qiáng)的HNBR硅烷改性聚氨酯密封膠的耐熱空氣老化性能較差。而改性蒙脫土由于其具有層狀硅酸鹽結(jié)構(gòu)的特點(diǎn),用其填充的膠料在加工過程中難以排除氣泡,且增強(qiáng)效果不太顯著。近年來,新型增強(qiáng)劑如甲基丙烯酸鋅(ZDMA)、改性蒙脫土對HNBR的增強(qiáng)研究受到廣泛關(guān)注, ZDMA的增強(qiáng)效果較好,但成本較高,且溫度ZDMA增強(qiáng)HNBR硅烷改性聚氨酯密封膠性能的影響研究鮮見報(bào)道。http://www.www.sunsage.net/
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